Carbon dioxide, as greenhouse gases go, is actually comparatively weak. Water vapor, by far the predominant greenhouse gas, is massively more effective in absorbing infrared radiation (which we experience as warmth) than CO2 (1), and massively more abundant in the troposphere(2), which is the region near the earth’s surface where climate takes place and life exists. Other greenhouse gases - methane, ozone, and the like, are stronger absorbers of infrared than CO2 but are present in such small amounts that they are of minor significance(3).
The only reason CO2 matters much at all is that its absorptive powers are largely concentrated in a very narrow but important range of about 13.5 to 16.4 microns in the infrared spectrum. It is in a part of that spectrum where most of the earth’s infrared radiation falls, between 7 and 50 microns. At 13.5 to 16.4 microns, it so happens, the earth’s infrared radiation level is quite high relative to other parts of the spectrum and water vapor’s absorptive powers relatively low. That leaves CO2 as the primary absorber in its narrow but important range (4).
Please note the graph labelled Radiance and Absorption. Reflecting what is depicted, recent calculations indicate CO2 presently accounts for about 19% (6) of the 33 degrees Celsius, or 91 degrees Fahrenheit, global warming (technically known as Radiative Forcing or RF) that prevents the earth from freezing over entirely. That has been a good thing.
However, as can be seen, that narrow band is now nearing saturation at present concentrations of CO2, meaning most of the earth’s radiation in that range is being absorbed, mostly by CO2 and to some extent by what water vapor does absorb in this range. There is little left for additional increases in atmospheric CO2 to absorb (7). The observed logarithmic relationship between actual CO2 levels and actual RF reflect these facts, as well as other factors, including downwelling radiation from the stratosphere.
(Incidentally, methane, also frequently mentioned as a greenhouse gas, is even more constrained by these considerations than CO2. Moreover, its even more limited absorption range is in an infrared region in which the earth’s radiation is very low. As can be realized from examining the Rhode chart above, it is a minor factor.)
It is well known to scientists that the correlation between CO2 levels and RF is not, as many appear to assume, a linear correlation, in which each X increase in CO2 would produce the same Y increase in RF. Instead, the relationship is logarithmic.(8) That means each additional X increase of CO2 contributes a successively smaller amount - about half - of additional RF than the one before.
The logarithmic curve can be calculated mathematically.(9) It is widely accepted that the best approximation to actual temperature changes since the period 1870-1900 is expressed as RF = ln5.35CO2, where RF is change in Radiative Forcing, hence temperature, expressed in degrees Celsius; ln means natural logarithm; and CO2 represents CO2 in the atmosphere expressed in parts per million (ppm).(10) The data to develop this curve were acquired empirically.
Observed RF in the industrial era till now therefore closely follows the theoretical curve (and also reflects methane, downwelling of radiation from warming in the stratosphere and above, feedback effects and any other factors at work, known or unknown) (See citations 1-5 in the text above). Average of the annual increases in CO2 concentration in the period 2010-2020 is about 2.44 ppm (2021 and 2022 were lower, but possibly for COVID related reasons)(11) To repeat the estimated (by IPCC) increase in that period of 1.1C at that decadal rate would take about 115 years. At that rate of increase in CO2, by 2100 mean global temperature would only increase about 0.6C, to about 1.9C in toto since the base period. Beyond that, the rate of increase continues to dwindle toward the infinitesimal at any rate of increase.
More practically, in the period ahead, through 2050, this logarithmic relationship would produce an increase in RF of perhaps 0.25C to 0.30C.
It happens that the maximum additional global warming the IPCC currently considers acceptable is preferably 1.5 degrees but in any case less than 2.0 degrees Celsius from an average of the period 1870-1900, and reckons about 1.1 degrees have already occurred, using average results over several years, which is about 0.4 degrees short of the preferred 1.5 degrees.(12) So, if the world takes absolutely no steps to reduce CO2 emissions and their calculable rise, global warming from that base period would likely add perhaps 1.45-1.40C degrees from that 1870-1900 base period by 2050 and somewhere around 1.8C by 2100. If the world adopts the extremely costly and draconian measures the IPCC and others are urging in order to “save the planet,” then global warming, anthropogenic or otherwise, will add something similar or perhaps slightly less according to IPCC, but the draconian measures could then be credited with “saving” the planet. Not being privy to the deliberations of those doing the urging, I will leave it to the reader to consider whether their choice is coincidence.
In recent decades CO2 levels have increased at a faster rate than previously, probably reflecting accelerated construction of fossil-fuel power plants in China, India, and numerous developing countries. That building trend seems likely to continue, perhaps even accelerate. If so, average temperatures may increase faster than indicated, and the levels at which additional warming from CO2 becomes negligible will then be reached sooner rather than later. “Negligible” is to some extent a subjective concept; to this author it appears to be in the region of 2.7-2.8C above the IPCC base.
The truth is, there is much more to global warming than human-caused emissions, CO2 included. Since the start of the industrial revolution, carbon dioxide is widely estimated to have risen from 280 ppm to the current 420 ppm-plus. That looks like a lot, and was added over a mere 170 years or so. But before that we had global warming for more than 10,000 years, at least since the end of the last Ice Age (albeit with some fluctuations), and there is evidence temperatures were actually somewhat warmer 9,000 years ago and again 4,500 to 8,000 years ago than they are today(13). Whatever the primary cause of that warming, it was not CO2. Atmospheric CO2 during those 10,000 years (and in previous ice-age cycles) was in the range of about 180 to 280 ppm,(14) much of the time below the preindustrial level of 280 ppm, though the gradual increase in CO2 during that period certainly contributed. Nor was it human activity. It was not all those power plants and factories and SUVs being operated by Stone Age cavemen while chipping arrowheads out of bits of flint. Whatever the cause was, it melted the mile-thick glaciers that in North America once extended south to Long Island and parts of New York City (15) into virtually complete disappearance (except for a few mountain remnants). That's one big greenhouse effect! If we are still having global warming - and I suppose we could presume we are, given this more than 10,000 year history - it seems highly likely that whatever it is, it would still be the overwhelmingly primary cause of continued warming. Perhaps we should be finding out what that cause (or set of causes) is, rather than worrying about CO2.
One likely important contributor to long-term changes, both in the current Holocene and preceding Pleistocene periods, as well as long before, is the so-called Milankovitch Cycles, recurring perturbations in and other effects of the earth's orbit and orientation caused by the combined gravitational effects of the other planets in the solar system, the earth's moon, and the sun. They are thought to explain the long-noted phenomenon of strikingly regular recurrences of ice ages and interglacial periods. A good description of the phenomenon can be found here: https://www.space.com/milankovitch-cycles
Consider the last eight grand Milankovitch cycles and the early strong upsurge in the current ninth, in which we are currently at or near previous peaks. Readings from the Vostok ice cores near the South Pole dating back 420,000 years (widely regarded as definitive) agree extremely closely with seabed sediment readings, indicating they were and are a worldwide phenomenon. Insolation at high northern latitudes correlates with both but not perfectly, indicating other factors are involved.
Yet even that trend-continuation today needs to be proved. Evidence is that the Medieval Warm Period centered on the 1200s was somewhat warmer than we are now(16), and climate was colder in the Little Ice Age culminating in the 1600s than it is now(17). (Whether the earlier Roman Warm Period around the time of Christ was as warm or was actually warmer than present is less clear.) So we are within the geologically recent range of normal up-and-down fluctuations without human greenhouse contributions that could be significant, or even measurable.
The idea that we should be spending trillions of dollars and hamstringing the economy of the entire world to reduce carbon dioxide emissions is beyond ludicrous in light of the facts above; it is insane. Furthermore, it sucks attention and resources from seeking the other sources of warming and from coping with - or taking advantage of - climate change and its effects in realistic ways.
The true motivation underlying the global warming movement is almost certainly ideological and political in nature, with a growing helping of greed now that many billions of dollars are being steered toward “controlling” global warming, and I predict that Anthropogenic Global Warming, as currently presented, will go down in history as the greatest fraud of all time. It makes Ponzi and Bernie Madoff look like pikers by comparison.
Many principal advocates, including many whose job description is “scientist,” arguing for fighting human-caused global warming have been demonstrably disingenuous[(18) and now you can see why. Those who knowingly have done this have proved they should not be trusted.
CITATIONS
(1) Absorption coefficient of carbon dioxide across atmospheric troposphere layer https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6174548/ See especially Figure 1, reproduced above, which sets out graphically the comparative infrared absorption of relevant greenhouse gases.
(2) Fundamentals of Physical Geography, 2nd Edition
by Micheal Pidwirney Concentration varies slightly with the growing season in the northern hemisphere. HYPERLINK http://www.physicalgeography.net/fundamentals/7a.html Water vapor varies from 0% in places like the Altacama desert in Chile to as much as 4% in equatorial ocean regions, and should easily average at least 1% worldwide. In that case, it would be 25 times more abundant than CO2. If (as seems reasonable) the global average is more like 2%, it would be 50 times more abundant.
(3) Ibid.
(4) Absorption coefficient of carbon dioxide across atmospheric troposphere layer https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6174548/
(5) Absorption coefficient of carbon dioxide across atmospheric troposphere layer Peng-Sheng Wei,∗. et al. https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6174548/ The authors work with satellite data (which necessarily incorporate absorption and other characteristics from the upper atmosphere as well as the troposphere) and other resources to calculate an estimate of what is happening in the troposphere alone.
(6) Journal of geophysical Research: Attribution of the present-day total greenhouse effect Gavin A. Schmidt, et al. https://agupubs.onlinelibrary.wiley.com/doi/full/10.1029/2010JD014287 See Table 1 and related text. The key figure for this discussion is the amount of absorption attributed to CO2 under all-sky conditions in the presence of other infrared absorbers, because those are the conditions that exist in reality. The others exist as perhaps-useful benchmarks for research. See text for details. The CO2 absorption is often reported as 25%, but that does not take into account absorption by H2O in the same ranges. Radiation absorbed by H2O obviously is no longer available to absorption by CO2 (and vice versa), reducing the effective absorption level of CO2.
(7) For another calculation of infrared absorption in the troposphere, Saturation of the Infrared Absorption by carbon dioxide in the Atmosphere International Journal of. Modern Physics Dieter Schildknecht. https://arxiv.org/pdf/2004.00708.pdf See Tables 1 through 7 and related figures and text. In particular, Tables 4 and 6 suggest absorption by CO2 Is somewhere between 80% (if you assume earth’s average relative humidity near the surface is 0%, which of course it is not) and 90% (if you assume average relative humidity is 85%). Note especially Fig. 3, which depicts the dramatic effect of adding absorption by H2O to that of CO2.
(8) Journal of Geophysical Research: Atmospheres Why logarithmic? A note on the dependence of radiative forcing on gas concentration Huang and Shahabadi https://agupubs.onlinelibrary.wiley.com/doi/pdf/10.1002/2014JD022466 - et al. Not only CO2 RF is logarithmic.
(9)https://www.desmos.com/calculator/w1g0o7umlq Also useful: https://www.rapidtables.com/calc/math/Log_Calculator.html
(10) The methodology is nicely summarized by the American Chemical Society here: https://www.acs.org/climatescience/atmosphericwarming/radiativeforcing.html Also see original paper: Meyhre, et al 1998 at https://agupubs.onlinelibrary.wiley.com/doi/pdf/10.1029/98GL01908 Note Table 3
(11)Annual Mean Growth Rate for Mauna Loa (of CO2) https://gml.noaa.gov/ccgg/trends/gr.html. Also, Mauna Loa Observatory https://www.co2.earth/daily-co2
(12) IPCC 2017 report, Ch. 1. https://www.ipcc.ch/site/assets/uploads/sites/2/2019/02/SR15_Chapter1_Low_Res.pdf - See the executive summary, et al. For easy quick reference, see FAQ on p. 79: FAQ 1.1: Why are we Talking about 1.5°C?
(13) Encyclopedia Britannica - Holocene Environment and Biota, et al. https://www.britannica.com/science/Holocene-Epoch/Holocene-environment-and-biota for early holocene. See also History of Earth’s Climate, Ch. 7, Brett Hansen http://www.dandebat.dk/eng-klima7.htm The citation here is of the English translation, which contains minor grammatical errors that do not materially affect content.
(14) https://courses.washington.edu/pcc588/readings/Sigman_Boyle-Glacial_CO2_Review-Na00.pdf
(15). The Narrows Flood – Post-Woodfordian Meltwater Breach of the Narrows Channel, NYC Charles Merguerian https://www.geo.sunysb.edu/lig/Conferences/abstracts-03/merguerian-03.pdf p. 2, et al.
(16) Britannica, same section as citation (11) https://www.britannica.com/science/Holocene-Epoch/Holocene-environment-and-biota. For historical period: Roman and Medieval Warm Periods also History of Earth’s Climate, Ch. 7, Brett Hansen http://www.dandebat.dk/eng-klima7.htm
(17) Encyclopedia Britannica
https://www.britannica.com/science/Little-Ice-Age
2 comments:
Muito bom seu artigo em pesquisas há uns 9 anos atrás li alguns artigos muito parecidos com estes e justamente fui muito prudente em não ser usado como massa de manobra,
Pois minha preocupação inicial não seria apenas o aquecimento global e sim a questão de todos os habitantes serem responsáveis pelo meio ambiente e as iniciativas para preservação ambiental deveriam aumentar muito nas décadas seguintes, resolvi colocar o nome Ciclo Legal Social ♻️ justamente por perceber que a terra tem seus ciclos e muito mais importante seria como poderíamos contribuir para redução da poluição Ambiental que é o fator chave para causas e efeitos dos problemas sociais que serão responsáveis pela redução populacional. Poluição do ar, das águas e poluição alimentar tudo geraria uma gigante crise social que poderia causar algo similar o que acontece nos dias de hoje com excessos de controles por parte de governos mundiais para submeter a população a servidão forçada.
Bom gostei muito do seu artigo mas acredito que muito que podemos ser agentes transformadores.
Keep up the good work. We must expose the truth before it's too late. Here is my own compilation of blatant climate fraud. http://informrevolution.blogspot.com/2021/11/man-made-climate-change-is-fraud.html
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